We were actually quite disappointed after we went to Ayyuthaya. It never came near the beauty of the historical park in Sukothai.
Ayuthaya is much more busy and touristy then Sukothai and the ruins aren't that well preserved. It doesn't have a park feeling because the sites are in the middle of the town, so when you are at a ruin, you can always here the traffic. Lots of the buddhas don't have heads anymore, and the ruins aren't well taking care of. At each temple/ruin you have to pay an entrance fee. It's mostly around 100 bath which isn't that expensive.
I wouldn't bother to come here if you have already seen Sukothai. Maybe if you see this before you go to Sukothai, you can enjoy the sites more.